1-(4-AMINOPHENYL)ETHANOL
- CasNo:14572-89-5
Product Description
Cost-effective and customizable 1-(4-AMINOPHENYL)ETHANOL 14572-89-5 supplier
- Molecular Formula: C8H11NO
- Molecular Weight: 137.181
- Appearance/Colour: powder
- Vapor Pressure: 0.00108mmHg at 25°C
- Melting Point: 70-74 °C(lit.)
- Refractive Index: 1.592
- Boiling Point: 288.5 °C at 760 mmHg
- PKA: 14.89±0.20(Predicted)
- Flash Point: 128.3 °C
- PSA： 46.25000
- Density: 1.117 g/cm3
- LogP: 1.90330
1-(4-AMINOPHENYL)ETHANOL(Cas 14572-89-5) Usage
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 50, p. 76, 1985 DOI: 10.1021/jo00201a015 |
InChI:InChI=1/C8H11NO/c1-6(10)7-2-4-8(9)5-3-7/h2-6,10H,9H2,1H3/t6-/m1/s1
14572-89-5 Relevant articles
Selective Hydrogenation by Carbocatalyst: The Role of Radicals
Ahmad, Muhammad Sohail,He, Huixin,Nishina, Yuta
, p. 8164 - 8168 (2019)
The selective hydrogenation of the nitro...
[N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions
Sánchez-Rodríguez,Fragoso-Medina,Ramírez-Meneses,Gouygou,Ortega-Alfaro,López-Cortés
, p. 49 - 54 (2018)
A pyrrolyl-containing [N-P]-ligand (L1) ...
Facile Synthesis and Tunable Porosities of Imidazolium-Based Ionic Polymers that Contain In Situ Formed Palladium Nanoparticles
Wang, Yangxin,Zhong, Hong,Li, Liuyi,Wang, Ruihu
, p. 2234 - 2240 (2016)
A series of porous imidazolium-based ion...
Synthesis and characterization of silica-coated magnetite nanoparticles modified with bis(pyrazolyl) triazine ruthenium(II) complex and the application of these nanoparticles as a highly efficient catalyst for the hydrogen transfer reduction of ketones
Mobinikhaledi, Akbar,Moghanian, Hassan,Ajerloo, Bahram,Dousti, Fatemeh
, (2020)
We present a facile and efficient method...
Study of liquid-phase dehydration of d,l-1-(4-Aminophenyl)ethanol in the presence of acid catalysts
Schul'tsev,Panarin
, p. 1309 - 1313 (2010)
Thermal acid-catalyzed liquid-phase dehy...
Hydrogenation of 4-nitroacetophenone over Rh/silica
Currall, Kathryn,Jackson, S. David
, p. 59 - 63 (2014)
The hydrogenation of 4-nitroacetophenone...
Ni Nanoparticles Stabilized by Poly(Ionic Liquids) as Chemoselective and Magnetically Recoverable Catalysts for Transfer Hydrogenation Reactions of Carbonyl Compounds
Vijayakrishna, Kari,Charan, K. T. Prabhu,Manojkumar, Kasina,Venkatesh, Sadhana,Pothanagandhi, Nellepalli,Sivaramakrishna, Akella,Mayuri, Pinapeddavari,Kumar, Annamalai Senthil,Sreedhar
, p. 1139 - 1145 (2016)
Imidazolium-based poly(ionic liquids) wi...
Optimizing selective partial hydrogenations of 4-nitroacetophenone via parallel reaction screening
Hawkins, Joel M.,Makowski, Teresa W.
, p. 328 - 330 (2001)
The hydrogenation of 4-nitroacetophenone...
Catalytic Transfer Hydrogenation with a Methandiide-Based Carbene Complex: An Experimental and Computational Study
Weismann, Julia,Gessner, Viktoria H.
, p. 16103 - 16112 (2015)
The transfer hydrogenation (TH) reaction...
Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions
Brünig, Julian,Kirchner, Karl,Veiros, Luis F.,Weber, Stefan
supporting information, p. 1388 - 1394 (2021/05/31)
In this paper, several Mn(I) complexes w...
Synthesis and Applications of (Pyridyl)imine Fe(II) Complexes as Catalysts in Transfer Hydrogenation of Ketones
Kumah, Robert T.,Vijayan, Paranthaman,Ojwach, Stephen O.
, p. 344 - 352 (2020/07/25)
Abstract: Chiral (pyridyl)imine Fe(II) c...
Ruthenium complex based on [N,N,O] tridentate -2-ferrocenyl-2-thiazoline ligand for catalytic transfer hydrogenation
Badillo-Gómez,Sánchez-Rodríguez,Toscano,Gouygou,Ortega-Alfaro,López-Cortés
, (2020/12/14)
A method for the synthesis of a new phos...
Highly Active Cooperative Lewis Acid—Ammonium Salt Catalyst for the Enantioselective Hydroboration of Ketones
Titze, Marvin,Heitk?mper, Juliane,Junge, Thorsten,K?stner, Johannes,Peters, René
supporting information, p. 5544 - 5553 (2021/02/05)
Enantiopure secondary alcohols are funda...
14572-89-5 Process route
-
-
99-92-3
p-aminobenzophenone
-
-
93453-80-6,14572-89-5
1-(4-aminophenyl)ethanol
-
-
589-16-2
4-aminoethylbenzene
| Conditions | Yield |
|---|---|
|
With
sodium hypophosphite monohydrate; 5%-palladium/activated carbon; tetrabutyl-ammonium chloride; sodium hydroxide;
In
2-methyltetrahydrofuran; water;
at 60 ℃;
for 4h;
Overall yield = 60 %; Overall yield = 82 mg;
Schlenk technique;
|
|
|
With
hydrogen;
In
1,3,5-trimethyl-benzene;
at 175 ℃;
for 16h;
under 37503.8 Torr;
Autoclave;
|
-
-
20062-24-2
4-azidoacetophenone
-
-
93453-80-6,14572-89-5
1-(4-aminophenyl)ethanol
-
-
99-92-3
p-aminobenzophenone
-
-
589-16-2
4-aminoethylbenzene
| Conditions | Yield |
|---|---|
|
With
palladium 10% on activated carbon; hydrogen;
In
tetrahydrofuran;
at 25 ℃;
for 1.5h;
under 760.051 Torr;
|
89%
5% 6% |
14572-89-5 Upstream products
-
99-92-3
p-aminobenzophenone
-
100-12-9
4-ethylnitrobenzene
-
100-19-6
(4-nitrophenyl)ethanone
-
10061-22-0
α-(2,4-dinitrophenyl)ethyl nitrate
14572-89-5 Downstream products
-
10517-48-3
2,3-bis-(4-amino-phenyl)-butane-2,3-diol
-
589-16-2
4-aminoethylbenzene
-
165117-08-8
3-Acetyl-5-chloro-N-[4-(2-hydroxyethyl)phenyl]-thiophene-2-sulfonamide
-
1520-21-4
4-vinyl benzylamine