Cinnamyl chloride
- CasNo:2687-12-9
Product Description
Reputable supplier selling Cinnamyl chloride 2687-12-9 with stock
- Molecular Formula: C9H9Cl
- Molecular Weight: 152.623
- Appearance/Colour: light yellow liquid
- Vapor Pressure: 0.0614mmHg at 25°C
- Melting Point: -19 °C(lit.)
- Refractive Index: n20/D 1.584(lit.)
- Boiling Point: 239.6 °C at 760 mmHg
- Flash Point: 96.6 °C
- PSA： 0.00000
- Density: 1.076 g/cm3
- LogP: 2.93860
Cinnamyl chloride(Cas 2687-12-9) Usage
|
General Description |
Cinnamyl chloride reacts regioselectively with aryl and alkenylgold(I) phosphanes in the presence of palladium catalyst in THF to afford the α-substitution product?. |
InChI:InChI=1/C9H9Cl/c10-8-4-7-9-5-2-1-3-6-9/h1-7H,8H2
2687-12-9 Relevant articles
-
Okuyama et al.
, p. 6749,6750,6751,6752 (1973)
-
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Okuyama et al.
, p. 3295 (1970)
-
-
Pocker,Buchholz
, p. 4033,4034 (1970)
-
Method for preparing 2-chloro-5-substituted pyridine
-
Paragraph 0015; 0061-0064; 0065; 0068, (2021/09/21)
The invention belongs to the technical f...
PdII/Novel Chiral Cinchona Alkaloid Oxazoline-Catalyzed Enantioselective Oxidative Cyclization of Aromatic Alkenyl Amides
Tian, Qinqin,Liu, Yulong,Wang, Xiaoyun,Wang, Xie,He, Wei
supporting information, p. 3850 - 3855 (2019/06/08)
A highly enantioselective PdII-catalyzed...
A Convenient Palladium-Catalyzed Carbonylative Synthesis of (E)-3-Benzylidenechroman-4-ones
Wang, Wei-Feng,Peng, Jin-Bao,Qi, Xinxin,Ying, Jun,Wu, Xiao-Feng
supporting information, p. 3521 - 3524 (2019/02/14)
A convenient palladium-catalyzed carbony...
Intermolecular Halogenation/Esterification of Alkenes with N-Halosuccinimide and Acetic Acid Catalyzed by 1,4-Diazabicyclo[2.2.2]octane
Pimenta, Laura S.,Gusevskaya, Elena V.,Alberto, Eduardo E.
supporting information, p. 2297 - 2303 (2017/07/07)
1,4-Diazabicyclo[2.2.2]octane (DABCO) is...
2687-12-9 Process route
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-
104-54-1
3-Phenylpropenol
-
-
2570-00-5
3,3-dichloro-1,2-diphenylcyclopropene
-
-
886-38-4
diphenylcyclopropenone
-
-
2687-12-9
cinnamyl chloride
| Conditions | Yield |
|---|---|
|
In
dichloromethane;
at 23 ℃;
for 0.05h;
Inert atmosphere;
|
92%
|
|
In
dichloromethane;
at 23 ℃;
for 0.05h;
|
-
-
C14 H17 NO
-
-
68-12-2,33513-42-7
N,N-dimethyl-formamide
-
-
18368-64-4
2-chloro-5-methylpyridine
-
-
2687-12-9
cinnamyl chloride
| Conditions | Yield |
|---|---|
|
With
bis(trichloromethyl) carbonate;
In
1,2-dichloro-ethane;
at 0 - 40 ℃;
for 2h;
|
2687-12-9 Upstream products
-
104-54-1
3-Phenylpropenol
-
4393-06-0
1-Phenyl-2-propen-1-ol
-
60-29-7
diethyl ether
-
122-04-3
4-nitro-benzoyl chloride
2687-12-9 Downstream products
-
85620-82-2
(E)-4-cinnamylmorpholine
-
33962-90-2
N,N-dimethylcinnamylamine
-
97526-50-6
triethyl-cinnamyl-ammonium; chloride
-
1142-24-1
N-cinnamylbenzenamine