Methyl 2-chlorobenzoate
- CasNo:610-96-8
Product Description
Quality manufacturer supply Methyl 2-chlorobenzoate 610-96-8 in stock with high standard
- Molecular Formula: C8H7ClO2
- Molecular Weight: 170.595
- Appearance/Colour: White to light yellow crystal powder
- Vapor Pressure: 0.0868mmHg at 25°C
- Melting Point: 233-235 °C
- Refractive Index: 1.5351-1.537
- Boiling Point: 225.4 °C at 760 mmHg
- Flash Point: 101.7 °C
- PSA： 26.30000
- Density: 1.224 g/cm3
- LogP: 2.12660
Methyl 2-chlorobenzoate(Cas 610-96-8) Usage
|
General Description |
Methyl 2-chlorobenzoate, a methyl 2-halobenzoate, is an ester. It can be synthesized from 2-chlorobenzoyl chloride. Its reduction with NaBH4 in diglyme at 162°C affords 2-chlorobenzyl alcohol. |
InChI:InChI=1/C8H7ClO2/c1-11-8(10)6-4-2-3-5-7(6)9/h2-5H,1H3
610-96-8 Relevant articles
Oxidative Coupling of Aldehydes with Alcohol for the Synthesis of Esters Promoted by Polystyrene-Supported N-Heterocyclic Carbene: Unraveling the Solvent Effect on the Catalyst Behavior Using NMR Relaxation
Di Carmine, Graziano,Ragno, Daniele,Massi, Alessandro,D'agostino, Carmine
, p. 4927 - 4931 (2020)
Heterogeneous organocatalysts hold great...
A Convenient and Stable Heterogeneous Nickel Catalyst for Hydrodehalogenation of Aryl Halides Using Molecular Hydrogen
Anwar, Muhammad,Beller, Matthias,Dastgir, Sarim,Junge, Kathrin,Leonard, David K.,Ryabchuk, Pavel
, (2022/02/03)
Hydrodehalogenation is an effective stra...
Br?nsted acid-catalyzed chlorination of aromatic carboxylic acids
Yu, Zhiqun,Yao, Hongmiao,Xu, Qilin,Liu, Jiming,Le, Xingmao,Ren, Minna
supporting information, p. 685 - 689 (2021/04/09)
The chlorination of aromatic carboxylic ...
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Antibacterial and Antiviral Activities of 1,3,4-Oxadiazole Thioether 4H-Chromen-4-one Derivatives
Cao, Xiao,Liu, Fang,Liu, Liwei,Liu, Tingting,Peng, Feng,Wang, Qifan,Xie, Chengwei,Xue, Wei,Yang, Jinsong
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610-96-8 Process route
-
-
67-56-1
methanol
-
-
609-65-4
o-chlorobenzoyl chloride
-
-
610-96-8
methyl chlorobenzoate
| Conditions | Yield |
|---|---|
|
With
triethylamine;
at 20 ℃;
for 10h;
|
95%
|
|
|
|
|
With
triethylamine;
In
dichloromethane;
at 0 ℃;
|
|
|
With
triethylamine;
In
dichloromethane;
at 0 ℃;
Inert atmosphere;
|
1.57 g
|
-
-
67-56-1
methanol
-
-
118-91-2
ortho-chlorobenzoic acid
-
-
610-96-8
methyl chlorobenzoate
| Conditions | Yield |
|---|---|
|
With
sulfuric acid;
for 4h;
Reflux;
|
100%
|
|
With
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione;
at 60 ℃;
for 8h;
|
100%
|
|
With
sulfuric acid;
Heating;
|
99%
|
|
With
1,3,5-trichloro-2,4,6-triazine; sodium carbonate;
at 50 ℃;
for 0.333333h;
Sonication;
|
94%
|
|
With
sulfuric acid;
at 78 ℃;
for 8h;
|
94.5%
|
|
With
thionyl chloride;
for 3h;
Ambient temperature;
|
91%
|
|
Acidic conditions;
|
86%
|
|
sulfuric acid;
|
81%
|
|
With
sulfuric acid;
at 20 ℃;
for 12h;
Inert atmosphere;
|
80%
|
|
With
Oxone;
In
toluene;
at 60 ℃;
for 48h;
Green chemistry;
|
74%
|
|
With
sulfuric acid;
for 10h;
Reflux;
|
60%
|
|
acid;
at 30 ℃;
Rate constant;
|
|
|
With
hydrogenchloride;
|
|
|
With
sulfuric acid;
|
|
|
With
diethyl ether; boron trifluoride;
|
|
|
With
sulfuric acid;
at 100 ℃;
for 0.0833333h;
under 5171.62 Torr;
Microwave irradiation;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
Acidic conditions;
Reflux;
|
|
|
With
sulfuric acid;
for 4h;
Reflux;
|
|
|
With
sulfuric acid;
Inert atmosphere;
Reflux;
|
|
|
Reflux;
Acidic conditions;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
Acidic conditions;
Reflux;
|
|
|
With
sulfuric acid;
|
|
|
With
sulfuric acid;
for 4h;
Reflux;
|
|
|
With
sulfuric acid;
for 6h;
Reflux;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
With
sulfuric acid;
at 70 ℃;
for 10h;
|
|
|
Acidic conditions;
|
|
|
With
sulfuric acid;
for 24h;
Reflux;
|
|
|
With
glycerol-based sulfonic acid functionalized carbon catalyst;
for 6h;
Reflux;
Green chemistry;
|
|
|
With
thionyl chloride;
at 20 ℃;
|
|
|
With
sulfuric acid;
for 5h;
Reflux;
|
|
|
methanol; ortho-chlorobenzoic acid;
at 0 ℃;
for 0.166667h;
With
thionyl chloride;
for 6h;
Reflux;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
With
sulfuric acid;
at 85 ℃;
|
|
|
With
sulfuric acid;
for 2h;
Reflux;
|
|
|
With
sulfuric acid;
|
|
|
With
sulfuric acid;
for 5h;
Reflux;
|
|
|
With
sulfuric acid;
for 8h;
Reflux;
|
|
|
With
sulfuric acid;
for 8h;
Reflux;
|
|
|
With
thionyl chloride;
at 20 ℃;
for 3h;
Reflux;
|
|
|
With
sulfuric acid;
for 3h;
Reflux;
|
610-96-8 Upstream products
-
67-56-1
methanol
-
609-65-4
o-chlorobenzoyl chloride
-
118-91-2
ortho-chlorobenzoic acid
-
57031-51-3
Methyl-tert.-butylperoxyoxalat
610-96-8 Downstream products
-
100398-32-1
2-(2'-pyrido)-2-chloroacetophenone
-
7579-40-0
benzyl 2-chlorobenzoate
-
3670-15-3
2-(2-chlorophenyl)propan-2-ol
-
97221-97-1
2-chloro-benzoic acid dodecyl ester